Adsorbed Layers on Surfaces. Part 2: Measuring Techniques - download pdf or read online

By Ch. Wöll (auth.), A. P. Bonzel (eds.)

Surface technological know-how is known as a comparatively younger clinical self-discipline, fascinated by the actual and chemical homes of and phenomena on fresh and coated reliable surfaces, studied lower than a number of stipulations. The adsorption of atoms and molecules on good surfaces is, for instance, this kind of situation, hooked up with kind of drastic alterations of all floor houses. An adsorption occasion is often saw in nature and located to be of technical value in lots of business strategies. accordingly, floor technological know-how is interdisciplinary through its very nature, and as such a massive middleman among basic and utilized research.

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Vac. Sci. Technol. A 12 (1994) 2063. Persson, B. N. , Volokitin, A. : Infrared reflection-absorption spectroscopy of dipoleforbidden adsorbate vibrations: Surf. Sci. 310 (1994) 314. , Liegener, C. : Angular-resolved autoionization study of CO on Ni(110): experiment and theory: Phys. Rev. B 49 (1994) 10557. Rieder, K. : Surface structural research with atom beam diffraction: helium versus neon: Surf. Rev. Lett. 1 (1994) 51. , Yannoni, C. , Kendrick, R. : Force detection of nuclear magnetic resonance: Science 264 (1994) 1560.

Chem. Phys. 108 (1998) 4212. Stipe, B. , Rezaei, M. : Science 280 (1998) 1732. :(1998) Surface "architecture" with large organic molecules: interface order and epitaxy: Surf. Sci. 402-404 (1998) 20. , Bradshaw, A. : SMART: an aberration-corrected XPEEM/LEEM with energy filter: Surf. Rev. Lett. 5 (1998) 1249. , Kostov, K. : Damping of molecular motion on a solid substrate: evidence for electron-hole pair creation: Phys. Rev. Lett. 80 (1998) 121. , Schwarz, U. : Dynamic scanning force microscopy at low temperatures on a noble-gas crystal: atomic resolution on the xenon (111) surface: Europhys.

Using this method it could also be demonstrated that ethylene, C2H4, adsorbs on a Cu(001)-surface in an essentially undistorted, planar adsorption geometry, whereas acetylene, C2H2, on the same surface shows a significant tilt of the C-H-bonds away from the C-C-bond [98FUH]. NEXAFS can be applied to a large number of adsorbate/substrate combinations. If the absorption is detected via the secondary electron yield, highly insulating substrates represent a problem. The situation is, however, considerably better than in conventional photoelectron spectroscopy, since small (several eV) shifts in the kinetic energy of the secondary electrons do not affect the positions of resonances in the spectra.

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